Coordination chemistry of new sulfur-containing ligands. 20. Preparation, characterization, and crystal and molecular structure of a severely distorted copper(II) N2S2 complex: [N,N'-tetramethylenebis(methyl 2-amino-1-cyclopentenedithiocarboxylato)]copper(II)
✍ Scribed by Bereman, Robert D.; Shields, Glen D.; Bordner, Jon.; Dorfman, Jay R.
- Book ID
- 121865177
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 642 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0020-1669
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## Abstract The stability constants of the Cu^II^ chelates with the tripodal heptadentate ligand tris{2‐[(2‐pyridylmethyl)amino]ethyl}amine (=__N__′‐(pyridin‐2‐ylmethyl)‐__N,N__‐bis{2‐[(pyridin‐2‐ylmethyl)amino]ethyl}ethane‐1,2‐diamine; tpaa), determined by potentiometry and UV spectrometry, show t
Two new polynuclear complexes of Cu II , [Cu 2 (fum)(µ-OH)(bpy) 2 (H 2 O)](NO 3 )•2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]•2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.