Coordination chemistry of molybdenum. Part III. EPR spectra of molybdenum(V) 8-hydroxyquinoline complexes and their relevance to the nature of molybdenum coordination in flavoenzymes

Coordination chemistry of molybdenum and

Coordination chemistry of molybdenum and tungsten—VIII. Oxomolybdenum(V) complexes of 8-hydroxyquinoline and relevance of EPR spectra to binding sites in flavoenzymes

✍ Charles A. McAuliffe; Barry J. Sayle 📂 Article 📅 1978 🏛 Elsevier Science ⚖ 437 KB

MoOCl3(THF)2 (THF = tetrahydrofuran) reacts with 8-hydroxyquinoline (QH) to form [MoQCI~(QH)~], which contains neutral monodentate ligands, [MoOCl(Q)~] ) and anionic bidentate l&rids, and the dimeric [M0203(Q)4], which contains anionic bidentate ligands and both terminal and bridging 0x0 donors. In