## Dedicated to Professor Andreas Pfaltz on the occasion of his 60th birthday Ene-1,1-diamines (ketene aminals, A) are a special class of olefins distinguished by a very electron rich and strongly polarized double bond. [1] This dipolar character is caused by the significant contribution from the m
✦ LIBER ✦
Coordination Chemistry of Ene-1,1-diamines and a Prototype “Carbodicarbene”
✍ Scribed by Alois Fürstner; Manuel Alcarazo; Richard Goddard; Christian W. Lehmann
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 391 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0044-8249
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## Abstract A key feature of tris(oxazolinyl)ethane (“trisox”) ligands, which have shown broad scope in asymmetric catalysis, is the orientation and steric demand of their oxazoline substituents. This, along with the modularity of their synthesis determines their coordination chemistry. The possibi