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Coordination Chemistry of Ene-1,1-diamines and a Prototype “Carbodicarbene”

✍ Scribed by Alois Fürstner; Manuel Alcarazo; Richard Goddard; Christian W. Lehmann


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
391 KB
Volume
47
Category
Article
ISSN
0044-8249

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Coordination Chemistry of Ene-1,1-diamin
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## Dedicated to Professor Andreas Pfaltz on the occasion of his 60th birthday Ene-1,1-diamines (ketene aminals, A) are a special class of olefins distinguished by a very electron rich and strongly polarized double bond. [1] This dipolar character is caused by the significant contribution from the m

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## Abstract A key feature of tris(oxazolinyl)ethane (“trisox”) ligands, which have shown broad scope in asymmetric catalysis, is the orientation and steric demand of their oxazoline substituents. This, along with the modularity of their synthesis determines their coordination chemistry. The possibi