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Coordination Chemistry of Cyclopropenylidene-Stabilized Phosphenium Cations: Synthesis and Reactivity of Pd and Pt Complexes

✍ Scribed by Kozma, Ágnes; Deden, Tobias; Carreras, Javier; Wille, Christian; Petuškova, Jekaterina; Rust, Jörg; Alcarazo, Manuel

Book ID: 125450277
Publisher: John Wiley and Sons
Year: 2014
Tongue: English
Weight: 502 KB
Volume: 20
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201303686

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## Abstract The __ortho__‐palladation of the iminophosphane ligand 6‐phenyl‐2‐[(2,6‐diisopropylphenyl)imino]pyridine (HL) with Pd(OAc)~2~ and PdCl~2~(PhCN)~2~ in benzene yields the neutral Pd–C,N,N pincer complexes Pd(OAc)(κ^3^‐C,N,N‐L) (1) and PdCl(κ^3^‐C,N,N‐L) (2), respectively. In the presence