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Coordination Chemistry of a Model for the GP Cofactor in the Hmd Hydrogenase: Hydrogen-Bonding and Hydrogen-Transfer Catalysis

✍ Scribed by Rauchfuss, Thomas B.; Wilson, Scott R.; Royer, Aaron M.


Book ID
115471995
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
68 KB
Volume
47
Category
Article
ISSN
0020-1669

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The manner of hydrogen-bonding to peptide selectors in enantiomer separation is examined with the help of a structural model. This model relies on a C 3 -symmetric trispeptide selector, which is stabilized by a network of distinct intramolecular hydrogen bonds. A combination of experimental and theo