Coordination behavior of the carboxylate group in organotin(IV) derivatives of 2-[(2′,4′,6′-tribromophenylamido)]benzoic acid and 3-[(2′,4′,6′-tribromophenylamido)]propenoic acid: Spectroscopic studies
✍ Scribed by S. Shahzadi; K. Shahid; S. Ali
- Book ID
- 111458036
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2007
- Tongue
- English
- Weight
- 223 KB
- Volume
- 33
- Category
- Article
- ISSN
- 1070-3284
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## Abstract Organotin(IV) complexes with general formula R~4 − __n__~SnL~__n__~ have been synthesized by the reaction of tri‐ and diorganotin chlorides with sodium salt of (__E__)‐3‐(4‐methoxyphenyl)‐2‐phenyl‐2‐propenoic acid in dry toluene, where RCH~3~, C~2~H~5~, __n__‐C~4~H~9~, C~6~H~5~, __n__
The complexes Me 2 SnL 2 (I), Me 3 SnL (II), Et 2 SnL 2 (III), n-Bu 2 SnL 2 (IV), n-Bu 3 SnL (V), n-Oct 2 SnL 2 (VI), Bz 2 SnL 2 (VII), and Ph 3 SnL (VIII), where "L" is (E)-3-(3-fluorophenyl)-2-phenyl-2-propenoate, have been prepared and structurally characterized by means of elemental analysis, in