but an unusually large second solvation shell such as Au(I). Investigations of metal ions coordinated to ammonia ligands have shown that coordination to hetero-atoms can accelerate the ligand exchange reaction rates by several orders of magnitude, e.g. for Cu(II) and Ni(II). Simulations of ions in a
β¦ LIBER β¦
Coordination and the size of ions and ligands
β Scribed by R.Thomas Myers
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 93 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0020-1650
No coin nor oath required. For personal study only.
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This article describes the synthesis and coordination chemistry of five broad types of ligands containing both phosphorus and sulfur donor centres, reviewing the literature up to the end of 1997. Phosphino thiolate ligands combine a phosphine centre with a thiol functionality (usually deprotonated o