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Coordination and oxidation-reduction in copper(I) and -(II) chloride-triethylphosphine-triethylchlorophosphonium chloride (triethyldichlorophosphorane) systems

✍ Scribed by Axtell, Darrell D.; Yoke, John T.

Book ID
126809378
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
545 KB
Volume
12
Category
Article
ISSN
0020-1669

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The potentiostatic reduction of Cu(II) in HCI solutions saturated by 0, was investigated to determine the competition of redox reactions between Cu(I), 0,) and Cl-. Cu(1) reacts with 0, to form OH radicals, which in turn oxidize Cl-to Cl radicals. When the radical scavenger toluene is added to the e