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Cooperativity of the Coil-Globule Transition in a Homopolymer: Microcalorimetric Study of Poly(N-isopropylacrylamide)

✍ Scribed by Tiktopulo, E. I.; Bychkova, V. E.; Ricka, J.; Ptitsyn, O. B.

Book ID
121199111
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
457 KB
Volume
27
Category
Article
ISSN
0024-9297

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Viscometric study of the coil-globule tr
Viscometric study of the coil-globule transition of poly(N-isopropylacrylamide) in solutions of surfactant
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## Abstract The coil‐globule transition of poly(__N__‐isopropylacrylamide) (systematic name: poly‐[1‐(isopropylaminocarbonyl)ethylene]) has been viscometrically investigated in low‐concentration aqueous sodium dodecyl sulfate solution. In this environment, even if the macromolecular coils collapse

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The coil-to-globule transition of two poly( N-isopropylacrylamide) (PNI-PAM) ionomers with different ionic contents (0.8 and 4.5 mol %), but similar weight average molar masses, in deionized water was investigated by a combination of static and dynamic light scattering. In spite of the large differe