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Cooperative interaction of H3O+ with 1,3-alternate tetrapropoxycalix[4]arene: NMR and theoretical study

✍ Scribed by Jaroslav Kříž; Jiří Dybal; Emanuel Makrlík; Jan Budka

Book ID
102951013
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
642 KB
Volume
46
Category
Article
ISSN
0749-1581

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Cooperative interaction of n-butylammoni
Cooperative interaction of n-butylammonium ion with 1,3-alternate tetrapropoxycalix [4]arene: NMR and theoretical study
✍ Jaroslav Kříž; Jiří Dybal; Jan Budka; Emanuel Makrlík 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 665 KB

## Abstract The interaction of 1,3‐alternate tetrapropoxycalix[4]arene (1) with __n__‐butylammonium ion (2) in CD~2~Cl~2~ was examined using ^1^H, ^13^C and ^14^N NMR spectroscopy and DFT (density functional theory) calculations. NMR shows that 1 forms with 2 an equimolecular hydrogen‐bonded comple