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Cooperative Effects: Stabilization of the Isoguanine Trimer

✍ Scribed by Gu, Jiande; Wang, Jing; Leszczynski, Jerzy


Book ID
126438292
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
382 KB
Volume
108
Category
Article
ISSN
0022-3654

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The chiral stabilities of β€œtrimeric keto
✍ Frank A. Anet; Issa Yavari πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 French βš– 199 KB

The 251 VHz lH NMR spectrum of the methylene protons of the all-cis isomer of trimeric \_\_ chloroacetone peroxide shows an AB quartet which remains sharp even at 155'C, indicating that the free-energy barrier for enantiomerization is higher than 24 kcal/mol, and that trimeric ketone peroxides are p