Cooperative assembly of a double-stranded hydrogen-bonded porphyrin zip

✍ Scribed by M.John Plater; Stuart Aiken; Grant Bourhill

• Book ID: 104230195
• Publisher: Elsevier Science
• Year: 2001
• Tongue: French
• Weight: 110 KB
• Volume: 42
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)00117-4

✦ Synopsis

A linear zinc porphyrin dimer has been used for the first time to stabilise two identical non-covalent aggregates by a combination of N-pyridyl zinc binding and hydrogen bonding. An improved multigram synthesis of 5,15-bis-(3,5-di-tertbutylphenyl)-10,20-bis(trimethylsilylethynyl)porphyrin is described.