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Conversions of allyl aryl sulfoxides under pummerer rearrangement conditions

✍ Scribed by N. V. Fedorov; M. V. Shevchenko; A. V. Anisimov; E. A. Viktorova

Book ID: 112355858
Publisher: Springer US
Year: 1985
Tongue: English
Weight: 249 KB
Volume: 21
Category: Article
ISSN: 0009-3122
DOI: 10.1007/bf00515059

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All attempts to convert compound (I) into (VI) fail. It is noteworthy that also DDQ reacts with (I) to give (III) in 37% yield. The structure of (III) is determined by X-ray analysis. Mechanistical aspects are discussed. -