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Conversions of 1- and 2-oxyadamantanes in the presence of a BF3·H3PO4 complex

✍ Scribed by E.A. Shokova; S.I. Knopova; K'en Nguyen Dang; B.A. Kazanskii (dec.)

Book ID
116042025
Publisher
Elsevier Science
Year
1973
Weight
441 KB
Volume
13
Category
Article
ISSN
0031-6458

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✍ Shin-ichi Satoh; Ryu Sato 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 275 KB

The treatment of SH-benzo[f+l,2,3,4+enathiepin ( B'lTP ) or 6H-benzo[g]-l,2,3,4,5-pentathiocin ( BFTC ) with alkenes in the presence of BF3aEt2 afforded trclns adducts, 2,3disubstituted ben~l, (1). which further reacted with alkenes to give cis adducts, 2,3disubstituted benz~l.4ditbiepanes (2).