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Conversion Under Hydrogen of Dichlorodifluoromethane over Supported Palladium Catalysts

✍ Scribed by B. Coq; J.M. Cognion; F. Figueras; D. Tournigant

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
693 KB
Volume
141
Category
Article
ISSN
0021-9517

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The heterogeneous catalytic hydrogenation of two isomeric cinchona alkaloids, cinchonidine and cinchonine, was studied over Pt/Al(2)O(3) in 1N H(2)SO(4) solution under 100 bar H(2) at 25 degrees C. Cinchonidine was transformed into two diastereomeric hexahydroderivatives by hydrogenation of ring A (