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Conversion of Ω-cyanoalkyl radicals to cycloalkanones by a new type of homolytic cyclization

✍ Scribed by Yu. N. Ogibin; é. I. Troyanskii; G. I. Nikishin

Book ID
112437719
Publisher
Springer
Year
1975
Tongue
English
Weight
84 KB
Volume
24
Category
Article
ISSN
1573-9171

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a-Aminonitriles were converted exclusively to the amides by 2-mercaptoethanol in anhydrous THF at -78°C by bubbling dry HCl gas Nitrile compounds have been hydrolyzed to amides by base in alcohols by HCl in HCOOH 2a or MeOH2b. by hv3, or by Ni4a, COAX, or Pd4' ion cataly:Isor ::::~~~~' thermal decom