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Conversion of α-chlorosulfenyl chlorides to ketones via α-chlorosulfen-amides. Use of thionyl chloride for oxidation of active methylene compounds

✍ Scribed by Kitaro Oka; Shoji Hara

Book ID
104243844
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
235 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis

Table I Synthesis of a-chlorosulfenyl chlorides from active methylene compounds Substrate C onditiona Product Yield sb ir (neat) C=O Benzyl phenyl ketoneC reflw,

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Use of thionyl chloride for imination of
Use of thionyl chloride for imination of active methylene compounds. Conversion of α-chlorosulfenyl chlorides to imines via thiocarbonyl S-imides
✍ Kitaro Oka; Shoji Hara 📂 Article 📅 1977 🏛 Elsevier Science 🌐 French ⚖ 242 KB

Recent reports la-f on the synthesis and chemistry of thiocarbonyl S-imides 2 prompted us to report a novel synthetic method for the preparation of a-imino carbonyl compounds and their derivatives from a-chlorosulfenyl chlorides derived from active methylene