Conversion of α-aminoesters to α-ketoesters
✍ Scribed by E.D. Thorsett
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 102 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Arylidene imines ofti-aminoesters react with nitrosobenzene at room temperature yielding a diarylnitrone and a Z-diimine.Adecuate mechanistic scheme is postulated to account for the products formed. Imines of d-aminoester
The title anions, when a-alkyl substituted, alkylate selectively in the y-position with hindered a-bromoesters. A lower degree of hindrance in either or both reactants tends to favour a-alkylation. The alkylation of the anion of Schiff bases derived from a-aminoesters has been widely exploited' sinc
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