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Conversion of Tungsten(IV) Oxo−Alkyne Complexes to Oxo−Vinylidene Complexes

✍ Scribed by Crane, Todd W.; White, Peter S.; Templeton, Joseph L.

Book ID
126029851
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
210 KB
Volume
18
Category
Article
ISSN
0276-7333

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## Abstract The thermal isomerizations of η^1^‐vinylidene complexes [(η^5^‐C~5~H~5~)(CO)(NO)W=C=CHR] [5a, R = Si(CH~3~)~2~C(CH~3~)~3~; 5c, R = C(CH~3~)~3~] as well as [(η^5^‐C~5~H~5~)(CO)(NO)Mo=C=CHC(CH~3~)~3~] (8), to the corresponding η^2^‐1‐alkyne complexes [(η^5^‐C~5~H~5~)(CO)(NO)W(η^2^‐H−C≡C−R