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Conversion of steroidal α-bromo ketones to ketols by means of hydrazine

✍ Scribed by Catsoulacos, Panayotis; Hassner, Alfred


Book ID
120360949
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
224 KB
Volume
32
Category
Article
ISSN
0022-3263

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S4N4·SbCl5 complex: A useful reagent for
✍ Kil-Joong Kim; Kyongtae Kim 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 189 KB

The reactions of sterically less hindered ~z-bromo alkyl and aryl ketones with tetrasulfur tetranitride.antimony pentachloride (S4N4"SbCIj) complex in toluene at reflux gave the corresponding a'-chloro ketones in good to excellent yields.