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Conversion of SO 2 to SO 3 by In Situ Photolysis of SO 2 and O 3 Mixtures Isolated in Argon Matrixes: Isotopic Effects †

✍ Scribed by Chaabouni, H.; Schriver-Mazzuoli, L.; Schriver, A.

Book ID
127081528
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
200 KB
Volume
104
Category
Article
ISSN
1089-5639

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✍ L. Schriver; D. Carrere; A. Schriver; K. Jaeger 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 488 KB

The mechanism of H$O4 formation via the reaction steps, SO1 t O$SO "\*' 3-(SO,: H,O) +H,SO,, has been investigated at low temperature in an argon matrix. Photooxydation of SO2 mainly occurs through the SO\*: O3 pairs. Photolysis of a SOI-H20-0, mixture did not lead to the H,SO, molecule. The I : 1 H