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Conversion of Phenols into Selenophenols: Seleno Newman-Kwart Rearrangement

✍ Scribed by Sørensen, Anne; Rasmussen, Brian; Agarwal, Shubham; Schau-Magnussen, Magnus; Sølling, Theis I.; Pittelkow, Michael

Book ID
121192627
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
656 KB
Volume
52
Category
Article
ISSN
0044-8249

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Conversion of sterically hindered phenol
Conversion of sterically hindered phenols into the corresponding N,N-dimethylarenesulfonamides via the Newman-Kwart rearrangement
✍ Anno Wagenaar; Jan B. F. N. Engberts 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 377 KB

## Abstract The 2‐alkyl‐ and 2,6‐dialkylbenzenesulfonyl chlorides 5a‐f were obtained in high yield by chlorination of the correspondingly substituted S‐aryl N,N‐dialkylthiocarbamates 4a‐g. These precursors have been synthesized via the Newman‐Kwart rearrangement of the corresponding O‐aryl N,N‐dial