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Conversion of olefins to ethylene ketals with mercuric acetate and palladium chloride

โœ Scribed by Donald F. Hunt; George T. Rodeheaver


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
264 KB
Volume
13
Category
Article
ISSN
0040-4039

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Synthesis of ฮฒ-mercuri ketones by the re
โœ Ilhyong Ryu; Koichi Matsumoto; Masato Ando; Shinji Murai; Noboru Sonoda ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 240 KB

Siloxycyclopropanes were quantitatively converted to B-acetoxymercuri ketones by the reaction with mercuric acetate. Successive treatment with palladium chloride or palladium chloride/carbon monoxide gave a-methylene ketones or y-ketoesters, respectively, in good yields.