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Conversion of Linear to Rhombic C 4 in the Gas Phase: A Joint Experimental and Theoretical Study

✍ Scribed by Blanksby, Stephen J.; Schröder, Detlef; Dua, Suresh; Bowie, John H.; Schwarz, Helmut


Book ID
127264673
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
297 KB
Volume
122
Category
Article
ISSN
0002-7863

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## Abstract The gas‐phase ion chemistry of GeF~4~ and of its mixtures with water, ammonia and hydrocarbons was investigated by ion trap mass spectrometry (ITMS) and __ab initio__ calculations. Under ITMS conditions, the only fragment detected from ionized GeF~4~ is GeF~3~^+^. This cation is a stron