Conversion of L-Cysteine into D-α-Amino Acids and Related Transformations
✍ Scribed by Rudolf O. Duthaler; Bernhard Wyss
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 134 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-193X
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## Abstract A new tripeptide (dimer), bis[(L‐cysteine‐__S__‐acetyl)‐L‐hemicystinyl(__S__^2^ → __S__^2^)‐D‐valine] (**6**) was synthesized by coupling __N__‐(__tert__‐butoxycarbonyl)‐__S__‐carboxymethyl‐L‐cysteine benzyl ester (**1**) with __S__‐trityl‐L‐cysteinyl‐D‐valine benzyl ester and subsequen