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Conversion of CO2in a trifluoroacetic acid

✍ Scribed by M. V. Vishnetskaya; M. S. Ivanova; E. M. Budynina; M. Ya. Mel’nikov

Book ID
110185596
Publisher
International Academic Publishing Co (Nauka/Interperiodica)
Year
2011
Tongue
English
Weight
162 KB
Volume
85
Category
Article
ISSN
0036-0244

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Infrared multiphoton dissociation of tritluoroacetic acid by a pulsed CO\* laser yields HF, COFz, CO1, CO, F3CC02CF2H and C2F, as photoproducts. Infrared fluorescence from the photoproducts, CO2 and COF,, is observed and analysed. Intermolecular V-V and V-R/T relaxation rate constants for CO1 decay