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Conversion of CO2 into Formate by Homogeneously Catalyzed Hydrogenation in Water: Tuning Catalytic Activity and Water Solubility Through the Acid—Base Equilibrium of the Ligand

✍ Scribed by Yuichiro Himeda

Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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Conversion of CO2 into Formate by Homoge
Conversion of CO2 into Formate by Homogeneously Catalyzed Hydrogenation in Water: Tuning Catalytic Activity and Water Solubility through the Acid–Base Equilibrium of the Ligand
✍ Yuichiro Himeda 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 293 KB

## Abstract This Microreview focuses on the recently developed hydrogenation of CO~2~ and hydrogen carbonate catalyzed by half‐sandwich complexes with 4,4′‐dihydroxy‐2,2′‐bipyridine (dhbp) and 4,7‐dihydroxy‐1,10‐phenanthroline (dhpt). An unprecedented high catalytic activity and reusability of the