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Conversion of clavulanic acid into thiadeoxa nuclear analogues

✍ Scribed by Peter C. Cherry; Derek N. Evans; Christopher E. Newall; Nigel S. Watson; Peter Murray-Rust; Judith Murray-Rust

Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
227 KB
Volume
21
Category
Article
ISSN
0040-4039

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✦ Synopsis

Addition of sulphur nuclaophilas to the diena (12) derived via the pen-2-em (5) from clavulanic acid provides the thiadaoxa a=loguas (14x). --X-ray analysis of the aster ( 14) shows the thermodynamically stable isomers to have the same relative staraoxemistry as clavulanic acid.

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