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Conversion of Carbon Dioxide to Oxalate by α-Ketocarboxylatocopper(II) Complexes

✍ Scribed by Takisawa, Hideyuki; Morishima, Yui; Soma, Shoko; Szilagyi, Robert K.; Fujisawa, Kiyoshi

Book ID
127203263
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
486 KB
Volume
53
Category
Article
ISSN
0020-1669

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✍ Mario Ruben; Dirk Walther; René Knake; Helmar Görls; Rainer Beckert 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 346 KB 👁 1 views

The reaction of oxalic amidines R 1 -N=C(NHR 2 )-C(NHR 2 )= N-R 1 with CH 3 MgX followed by uptake of CO 2 results in the formation of the trimeric carbamato complexes [R 1 -N= C(NR 2 -COO)-C(NR 2 COO)=N-R 1 ] 3 Mg 3 (THF) 6 (2a: R 1 = R 2 = Ph; 2b: R 1 = R 2 = p-tolyl) as the thermodynamically stab