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Conversion of Acid Chlorides to Substituted Acetylenes with Tungsten Alkylidynes

✍ Scribed by Connell, Brian T.; Kirkland, Thomas A.; Grubbs, Robert H.

Book ID
126013019
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
60 KB
Volume
24
Category
Article
ISSN
0276-7333

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Conversion of oleic acid to 17- and 18-s
Conversion of oleic acid to 17- and 18-substituted stearic acid derivatives by way of the β€žacetylene zipper”
✍ Augustin, Kim E. ;SchΓ€fer, Hans J. πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 402 KB

## Abstract Stearolic acid (2) was prepared from oleic acid (1) and converted to 4, 5, and 7 by way of the β€žacetylene zipper”︁ reaction. Compounds 5 and 7 were transformed to the (Ο‰ – 1) ketones 8 and 9 and dimerized by way of the Glaser coupling reaction to 11 and 12. At daylight, 12 polymerizes t