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Conversion of a Singlet Silylene to a stable Biradical

✍ Scribed by Mondal, Kartik Chandra; Roesky, Herbert W.; Schwarzer, Martin C.; Frenking, Gernot; Tkach, Igor; Wolf, Hilke; Kratzert, Daniel; Herbst-Irmer, Regine; Niepötter, Benedikt; Stalke, Dietmar


Book ID
120051929
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
484 KB
Volume
52
Category
Article
ISSN
0044-8249

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In an attempt to reinforce our recent experiments on silylene-oxygen adducts, the structure and kinetic stability of silanone oxide (H2SiOO) in the singlet state have been investigated at several levels of theory. It is found that &none oxide has a nonplanar, pyramidal structure and undergoes rapid