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Conversion of 2-diazohexose sugar derivatives into five-carbon acetylenic and enol ester derivatives

โœ Scribed by Gelas-Mialhe, Yvonne; Horton, Derek


Book ID
126226257
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
520 KB
Volume
43
Category
Article
ISSN
0022-3263

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Conversion of Fatty Acids and Derivative
โœ Quermann, Rolf ;Maletz, Reinhard ;Schรคfer, Hans J. ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 507 KB

## Abstract The enolates of fatty acid methyl esters 1aโ€“g are dimerized in good yields (56 to 73%) by means of oxidative coupling with copper(II) bromide to dialkylated succinic esters 2aโ€“g. The configuration of __meso__โ€2a was established by independent synthesis. On treatment with ozone the unsat