Conversion of 2-acetamido-2-deoxy-d-glucose into 2-acetamido-2,6-dideoxy-d-galactose (N-acetyl-d-fucosamine) and its benzyl-3-O-benzyl glycosides
โ Scribed by Derek Horton; Hiromichi Saeki
- Book ID
- 108307770
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 535 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0008-6215
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๐ SIMILAR VOLUMES
Condensation of benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-a-D-galactopyranoside with 2,3,4-tri-o-acetyl-a-D-fucopyranosyl bromide in 1: 1 nitromethane-benzene, in the presence of powdered mercuric cyanide, afforded benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-0-(2,3,4-tri-O-acetyl-P-D-fucopyran
Treatment of benzyl 2-acetamido-2-deoxy-alpha-D-galactopyranoside with 4-methoxybenzaldehyde dimethyl acetal in N,N-dimethylformamide in the presence of 4-toluenesulfonic acid afforded the 4,6-O-(4-methoxybenzylidene) acetal, which was glycosylated with 2,3,4,6-tetra-O-acetyl-alpha-D-galactopyranosy