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Convergent Formal Synthesis of (.+-.)-Heliannuols A, K, and L from a Common Intermediate.

✍ Scribed by Frederic Lecornue; Jean Ollivier

Publisher
John Wiley and Sons
Year
2004
Weight
22 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract An efficient, general synthetic route to the bengamide family of antitumor agents from a common polyol thioester is described. Consecutive aldol condensations afford the protected polyol thioester side chain suitable for coupling to the bengamides. A novel chiral‐phase‐transfer‐catalyze