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Convenient synthesis of (triphenyl)germyl and (triphenydstannyl substituted allenes

✍ Scribed by K. Ruitenberg; H. Westmijze; H. Kleijn; P. Vermeer


Book ID
103223998
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
539 KB
Volume
277
Category
Article
ISSN
0022-328X

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## The reaction of pivaloylethoxyacetylene with silicon halides, which has been found to occur as a 1,4-addition, leads to allenic ethers, which readily eliminate ethyl halides and are converted to previously unknown types of ketenes-stable element-substituted acylketenes. Gerrnanium-substituted acy