Convenient synthesis of new amphiphilic triphenylphosphine analogues for aqueous biphasic catalysis
✍ Scribed by Laurent Caron; Michaël Canipelle; Sébastien Tilloy; Hervé Bricout; Eric Monflier
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- French
- Weight
- 183 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
The synthesis of tris(4-( 1-oxoperfluorooctyl)-2-perfluorooctylphenyl)phosphite and tris(2,4bis(perfluorooctyl)phenyl)phosphite from commercially available 1-iodoperfluorooctane and 2,4-dibromophenol is described. The stability and the solubility of these new compounds are reported.
## Abstract Mono‐ and disulfonated amphiphilic versions of triphenylphosphane (PPh~3~) and cyclohexyl(phenyl)phosphane were easily synthesized from commercial reagents and sulfuric acid. The behaviour of these phosphanes in solution was investigated by surface tension, isothermal titration calorime
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