CONVENIENT SYNTHESIS OF METHYL L - GLYCERO - D - MANNO -HEPTOPYRANOSIDE
โ Scribed by Yamasaki, Ryohei; Takajyo, Akihiko; Kubo, Hiroyuki; Matsui, Takeaki; Ishii, Kazuyuki; Yoshida, Masashi
- Book ID
- 126494434
- Publisher
- Taylor and Francis Group
- Year
- 2001
- Tongue
- English
- Weight
- 416 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0732-8303
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Five Monophosphates of Methyl L-glycero-ฮฑ-D-manno-Heptopyranoside: Synthesis, Hydrolysis and Migrations. -The title compounds are prepared from suitably protected methyl ฮฑ-Dmannopyranosides according to a reported protocol based on a one-carbon-atom chain elongation at C-6 via Swern oxidation
The reaction of (phenyldimethyl)silylmethyl.magnesiu chloride with benzyl 2,3,4tri-0-benzyl-a-D-manno-hexodialdo-1,5-pyranoside affords the corresponding L-glycero-Dmanno-addition product having at C-7 the phenyldim:thylsilyl (PDMSi) group. The latter silanyl compound survived benzylation as veil as