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CONVENIENT SYNTHESIS OF 1-ACETYL-2,2-DIMETHYL-3-ARYLCYCLOPROPANES

✍ Scribed by Muthusubramanian, Lakshmi; Mitra, Rajat B.


Book ID
126883439
Publisher
Taylor and Francis Group
Year
2008
Tongue
English
Weight
283 KB
Volume
40
Category
Article
ISSN
0030-4948

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(βˆ’)-cis-1-Acetyl-3-ethynyl-2,2-dimethylΒ­
✍ Malak, Muhammad H. ;Lalancette, Roger A. ;Thompson, Hugh W. πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 152 KB

The title compound, C~10~H~14~O, adopts a conformation typical of __cis__-1,3-disubstituted cyclobutanes, with the ring flexed out of planarity so that the substituents are maximally separated. The two intermolecular Cβ€”H...O=C close contacts found include one involving the acetylenic H atom.