Convenient Preparation of Functionalised Polymer-Based Resins via an Economical Preparation of Chloromethylated Polystyrene Resins (Merrifield Type)

Solid-phase synthesis on functionalised

Solid-phase synthesis on functionalised fluoropolymer resins. Part 2: Preparation and properties of functional Merrifield-type resins possessing a perfluorinated polymer backbone

✍ Shuyuan Liu; Mahmoud Akhtar; David Gani 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 116 KB

Monomers a,b,b-tri¯uorostyrene and 4-methyl-a,b,b-tri¯uorostyrene were prepared and were copolymerised under free-radical emulsion conditions to give highly stable, well de®ned lipophilic polymer resins. Benzylic halogenation of the polymer products gave 4-chloromethyl and 4-bromomethyl derivatives