✦ LIBER ✦
Convenient access to two enantiomeric oxirane synthons bearing a quaternary gem-dimethyl carbon center: Synthesis of 3S-(+) and 3R-(−)-2,2-dimethyl-3,4-oxo-1-butanol from R-(−)-pantolactone
✍ Scribed by Pierre Lavallée; Réjean Ruel; Louis Grenier; Martine Bissonnette
- Book ID
- 104218185
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 220 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Starting with the commercially available R(-)-Pantolactone and using three different pathways, the synthesis of two new and potentially use ful enantiomeric hydroxy epoxide s ynthons possess ing a quat ernary gem-dimethyl carbon center is r eport ed.