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Controlling the Secondary Structure of Nonbiological Oligomers with Solvophobic and Coordination Interactions

✍ Scribed by Ryan B. Prince; Takashi Okada; Jeffrey S. Moore


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
176 KB
Volume
38
Category
Article
ISSN
0044-8249

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## Complexes Me 2 SnCl(SPy) and Me 2 SnCl(SPym) (HSPy = 2-mercaptopyridine; HSPym = 2-mercaptopyrimidine), from ethanol solutions, interact with aqueous calf-thymus DNA yielding condensed phases with probable Me 2 Sn(SPy,-SPym) (DNA monomer) stoichiometries of 1:1; the condensation of DNA is inferr