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Controlling the ligating behaviour of biologically important p-hydroxybenzoate towards copper(II) by the use of nitrogen bases: Synthesis, characterization and single crystal X-ray structure determination of [trans-Cu(en)2(H2O)2](L1)2 · 2H2O and [cis-Cu(L1)2(L2)2] where en = ethylenediamine, L1 = p-hydroxybenzoate, L2 = 3-picoline

✍ Scribed by Raj Pal Sharma; Ajnesh Singh; Anju Saini; Paloth Venugopalan; Alessandra Molinari; Valeria Ferretti


Book ID
108213061
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
649 KB
Volume
923
Category
Article
ISSN
0022-2860

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To investigate the spectra-structure relationship, three new copper(II) complex salts of composition [trans-Cu(en) (where L 1 = ibuprofenate, L 2 = o-methoxybenzoate and L 3 = p-ethoxybenzoate) were obtained when ethylenediamine was added to 'Cu(L) 2 ' (L = L 1 /L 2 /L 3 ) in methanol-water solutio