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Controlling Factors in the Synthesis of Cucurbituril and Its Homologues

✍ Scribed by Day, Anthony; Arnold, Alan P.; Blanch, Rodney J.; Snushall, Barry


Book ID
111652002
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
78 KB
Volume
66
Category
Article
ISSN
0022-3263

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## Abstract D,L‐2,6‐Diaminopimelic‐(2‐^14^C) acid was prepared by alkylation of diethyl acetamidomalonate‐(2‐^14^C) with 5‐bromo‐N‐phthaloyl‐L‐norvaline methyl ester and hydrolysis of the condensation product. Depending on the alkylation conditions, partial or complete racemisation takes place and