## Communications Several novel porphyrins mimicking the self-assembly ability of the natural bacteriochlorophylls c, d, and e have been synthesized in high yields. These artificial antenna systems should be able to harvest sunlight even under low-light illumination conditions, as implied by the e
โฆ LIBER โฆ
Controlling Chirality and Optical Properties of Artificial Antenna Systems with Self-Assembling Porphyrins
โ Scribed by Teodor Silviu Balaban; Anil Dnyanoba Bhise; Matthias Fischer; Myriam Linke-Schaetzel; Christian Roussel; Nicholas Vanthuyne
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 245 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0044-8249
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The standard RP-HPLC mode with a conventional octadecylsilicapacked column and the chiral chelate (-)(M)(,โณ)-[4,4ะ-((1S)-methyl-(2R)propylethanediyldiimino)bis(pent-3-en-2-onato)]nickel(II), with a flexible, helically selfassembled structure, as the chiral selector in a mobile phase of acetonitrile-