## Abstract The present studies provide the first example of controlled free radical polymerization of a cyclopolymerizing monomer, i.e. diallyldimethylammonium chloride (DADMAC) via reversible addition fragmentation chain transfer (RAFT) chemistry in the presence of trithiocarbonate agent in aqueo
β¦ LIBER β¦
Controlled/Living Ring-Closing Cyclopolymerization of Diallyldimethylammonium Chloride via the Reversible Addition Fragmentation Chain Transfer Process
β Scribed by Assem, Yasser; Chaffey-Millar, Hugh; Barner-Kowollik, Christopher; Wegner, Gerhard; Agarwal, Seema
- Book ID
- 126452205
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 148 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0024-9297
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## Abstract **Summary:** The RAFTβCLDβT methodology is demonstrated to be not only applicable to 1βsubstituted monomers such as styrene and acrylates, but also to 1,1βdisubstituted monomers such as MMA. The chain length of the terminating macromolecules is controlled by CPDB in MMA bulk free radica