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Controlled/“Living” Radical Polymerization. Homogeneous Reverse Atom Transfer Radical Polymerization Using AIBN as the Initiator

✍ Scribed by Xia, Jianhui; Matyjaszewski, Krzysztof

Book ID
115460309
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
114 KB
Volume
30
Category
Article
ISSN
0024-9297

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Well-de®ned polystyrenes with an a-C(CH 3 ) 2 (CN) and an v-chlorine atom end-groups, and narrow polydispersity (M n = 3000±4000 g mol À1 , M w /M n = 1.3±1.4) have been synthesized by a radical polymerization process using 2,2'-azobisisobutyronitrile(AIBN)/FeCl 3 /PPh 3 initiation system. When the