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Controlled Synthesis of an ABC Miktoarm Star-Shaped Copolymer by Sequential Ring-Opening Polymerization of Ethylene Oxide, Benzyl β-Malolactonate, and ε-Caprolactone

✍ Scribed by Rieger, J.; Coulembier, O.; Dubois, P.; Bernaerts, K. V.; Du Prez, F. E.; Jérôme, R.; Jérôme, C.


Book ID
126046938
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
223 KB
Volume
38
Category
Article
ISSN
0024-9297

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Synthesis of AB2 3- and AB4 5-Miktoarm S
✍ Yozo Miura; Yumi Sakai; Keisuke Yamaoka 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 186 KB

## Abstract Summary: Well‐defined AB~2~ 3‐ and AB~4~ 5‐miktoarm star copolymers were prepared by combination of ring‐opening polymerization (ROP) and nitroxide‐mediated radical polymerization (NMRP) using dendritic tri‐ and penta‐functional initiators. Initially, two kinds of dendritic initiators h