Controlled Synthesis of a New, Soluble, Conjugated Metallopolymer Containing Ruthenium Chromophoric Units
✍ Scribed by Rasmussen, Seth C.; Thompson, David W.; Singh, Virendra; Petersen, John D.
- Book ID
- 120425442
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 142 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0020-1669
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## Abstract **Summary:** A class of new, soluble, __π__‐conjugated polymers containing a fumaronitrile unit in the main chain were synthesized by the reaction between di(4‐bromophenyl)fumaronitrile and bis(2,2‐dimethylpropane‐1,3‐diyl)‐1,4‐dialkoxyphenylene‐2,5‐diborate employing palladium catalyst
**A new 1,10‐phenanthroline‐containing π‐conjugated polymer,** the color of which can be tuned from blue to red by metal complexation, has been synthesized. The polymer responds sensitively to various metal ions due to its high coordinating ability, and the Figure shows emission from the polymer–met