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Controlled Synthesis of 2-Acetyl-6-carbethoxypyridine and 2,6-Diacetylpyridine from 2,6-Dimethylpyridine.

✍ Scribed by Biyun Su; Jianshe Zhao; Yong Cui; Yongqing Liang; Wenhua Sun


Publisher
John Wiley and Sons
Year
2006
Weight
19 KB
Volume
37
Category
Article
ISSN
0931-7597

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Enantioconvergent synthesis of (βˆ’)-(S)-
✍ V.G. Zaitsev; A.L. Mikhal'chuk πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 129 KB πŸ‘ 1 views

## Abstract The synthesis of enantiomerically pure (βˆ’)‐(__S__)‐ and (+)‐(__R__)‐2‐acyl‐3,6‐dihydroxycyclohex‐2‐enone starting from diastereomerically pure N‐tosyl‐(__S__)‐proline esters 3‐methoxy‐6‐hydroxycyclohex‐2‐enone **1** is presented. An enantioconvergent synthesis of either (βˆ’)‐(__S__)‐ and