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Controlled synthesis and reversible oxidation of a thiolate-bridged macrocyclic dinickel(II) complex

✍ Scribed by Brooker, Sally; Croucher, Paul D.; Roxburgh, Fiona M.


Book ID
120666686
Publisher
The Royal Society of Chemistry
Year
1996
Tongue
English
Weight
1003 KB
Volume
14
Category
Article
ISSN
1472-7773

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Controlled Thiolate Coordination and Red
✍ Sally Brooker; Paul D. Croucher; Tony C. Davidson; Geoffrey S. Dunbar; Corina U. πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 550 KB

A single crystal X-ray analysis of [Ni 2 L1](ClO 4 ) 2 β€’ MeCN β€’ 1/ thiocyanate ions, forming [Ni 2 L1(NCS) 2 ] 4 and [Ni 2 L2(NCS) 2 ] 5 respectively, whereas 3 does not. Single crystal X-ray 4 H 2 O, 1a [formed directly from a mixture of nickel(II) template ions, 2,6-diformyl-4-methyl-thiophenolate